Painful Quandary

Whenever an opponent casts a spell, that player loses 5 life unless they discard a card.

Forgotten Ancient

Whenever a player casts a spell, you may put a +1/+1 counter on this creature.
At the beginning of your upkeep, you may move any number of +1/+1 counters from this creature onto other creatures.

Ishai, Ojutai Dragonspeaker

Flying
Whenever an opponent casts a spell, put a +1/+1 counter on Ishai.
Partner (You can have two commanders if both have partner.)

Dragonlair Spider

Reach
Whenever an opponent casts a spell, create a 1/1 green Insect creature token.

Forced Fruition

Whenever an opponent casts a spell, that player draws seven cards.

Mana Breach

Whenever a player casts a spell, that player returns a land they control to its owner's hand.

Managorger Hydra

Trample
Whenever a player casts a spell, put a +1/+1 counter on this creature.

Ice Cave

Whenever a player casts a spell, any other player may pay that spell's mana cost. If a player does, counter the spell. (Mana cost includes color.)

Oppression

Whenever a player casts a spell, that player discards a card.

Counterbalance

Whenever an opponent casts a spell, you may reveal the top card of your library. If you do, counter that spell if it has the same mana value as the revealed card.

Noosegraf Mob

This creature enters with five +1/+1 counters on it.
Whenever a player casts a spell, remove a +1/+1 counter from this creature. If you do, create a 2/2 black Zombie creature token.

Lurking Predators

Whenever an opponent casts a spell, reveal the top card of your library. If it's a creature card, put it onto the battlefield. Otherwise, you may put that card on the bottom of your library.

Kaervek the Merciless

Whenever an opponent casts a spell, Kaervek deals damage equal to that spell's mana value to any target.

Tovolar's Magehunter

Whenever an opponent casts a spell, this creature deals 2 damage to that player.
At the beginning of each upkeep, if a player cast two or more spells last turn, transform this creature.

Mondronen Shaman

At the beginning of each upkeep, if no spells were cast last turn, transform this creature.

Mondronen Shaman // Tovolar's Magehunter

Cemetery Gatekeeper

First strike
When this creature enters, exile a card from a graveyard.
Whenever a player plays a land or casts a spell, if it shares a card type with the exiled card, this creature deals 2 damage to that player.

Curse of Vengeance

Enchant player
Whenever enchanted player casts a spell, put a spite counter on this Aura.
When enchanted player loses the game, you gain X life and draw X cards, where X is the number of spite counters on this Aura.

Chancellor of the Annex

You may reveal this card from your opening hand. If you do, when each opponent casts their first spell of the game, counter that spell unless that player pays {1}.
Flying
Whenever an opponent casts a spell, counter it unless that player pays {1}.

Hunting Grounds

Threshold — As long as seven or more cards are in your graveyard, this enchantment has "Whenever an opponent casts a spell, you may put a creature card from your hand onto the battlefield."